Search Google Appliance

 

methods

Department of Physics
Portland State University

Current Research Areas

Isotopic atmospheric methane

Emissions from rice agriculture

Role of trees in the methane budget

Methyl halide emissions from estuaries

Carbon flux from cities

Method development

 

 

 

 

Method Development

At low concentrations in the atmosphere, greehouse gases (e.g., methane and nitrous oxide) and other important trace species can be challenging to measure with sufficient precision to characterize spatial and temporal variability in the Earth's system. Additional challenges in senstivity and precision are presented when measuring isotopic composition of atmospheric trace species due to interfering isobars and isotopic fractionation effects in measurement.

Driven by a need to collect data more rapidly than ever, our research group develops and uses novel analytical techniques to measure atmospheric trace species. These include advances in gas chromarography, mass spectrometry and optical cavity enhanced techniques.

Recent published work in method development for cavity ring-down spectroscopy can be found in Review of Scientific Instruments:

Bostrom, G., D. Atkinson, A. Rice, The discrete Fourier transform algorithm for determining decay constants - Implementation using a field programmable gate array, Review of Scientifc Instruments, 86, 043106, 2015

and Optics Letters:

Bostrom, G., A. Rice, D. Atkinson, Optical injection unlocking for cavity ringdown spectroscopy, Optics Letters, 39, 14., 2014

and in a full Ph.D. dissertation by Dr. Gregory Bostrom:

Bostrom, Gregory Alan, Modifications to a Cavity Ringdown Spectrometer to Improve Data Acquisition Rates, Dissertations, Portland State University, Paper 2208, 2015

Information on method development of isotopic atmospheric methane measurements can be found in a dissertation by Dr. Doaa Teama:

Teama, Doaa Galal Mohammed, A 30-Year Record of the Isotopic Composition of Atmospheric Methane, Dissertation, Portland State University, 2013

Information on our Analytical Services