Research in the Wamser Group
at Portland State University


Electropolymerizations

Polymer grows directly on an electrode


We are investigating the oxidative electropolymerizations of aminoporphyrins, which form conductive polymers apparently analogous to polyaniline. These polymers are being studied with respect to their structure, conductivity, acid-base, and redox properties. We have also started investigating copolymerizations with aniline. In particular, we would like to use these conductive polymers as components of a TiO2 solar cell. Aminoporphyrins and the related hydroxyporphyrins have an interesting set of spectroscopic properties, chracteristic of what are called hyperporphyrins, and we are also investigating the uv-visible and fluorescence spectroscopy of these compounds, in particular correlating their redox chemistry with their acid-base chemistry.


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