Organic Chemistry III

Professor Carl C. Wamser

Quiz 23,24

Chem 336 - Spring 2005

1. (2 points) Arrange the following in order with respect to the property indicated.

a) acidity

MIDDLE / / LEAST / / MOST

b) rate of substitution by ammonia

MOST / / MIDDLE / / LEAST


2. (4 points) Complete the following reactions by adding the missing part:

a)

b)

c)

d)


3. (4 points) Write a complete mechanism for the substitution reaction below. Show all steps and all resonance forms for any intermediates. Identify the best resonance form for the delocalized intermediate.