Chem 336 - Spring 2002
Organic Chemistry III
Dr. Carl C. Wamser

Chapter 20 Homework

Carey, pages 822 - 830:
Problems 20.25 - 20.45


1. Write complete names for each of the following:

a)

4-oxo-5-phenylpentanenitrile




b)

(S)-4-bromo-N-propylpentanamide




c)

isopropyl cyclopentanecarboxylate




2. A typical protein linkage is an amide bond (also called a peptide bond), such as might be found in N-methylacetamide. Proteins are typically hydrolyzed in strong acid. Write a complete mechanism for the acid-catalyzed hydrolysis of N-methylacetamide.




3. A typical fat has ester functional groups (most typically it is a triester between three fatty acids and glycerol). Glycerol is 1,2,3-propanetriol, and a fatty acid might be decanoic acid. Write the structure for the triester made from these components.




4. Using butanoic acid as the only organic starting material, show how to prepare:

a) 1-butanol




b) 1-bromobutane




c) butyl butanoate




d) butanamide




e) pentanoic acid