Organic Chemistry II |
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Professor Carl C. Wamser |
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Chem 335 - Winter Term |
Quiz 13 |
1. (3 points) There are only two isomers of dichloroethane. In their proton NMR spectra, A has only one singlet and B has two absorptions. Identify A and B, and describe the expected appearance of the two absorptions of B.
2. (1 point) Which of the isomers of C4H9Br would show exactly three absorptions in its C-13 NMR spectrum?
3. (3 points) In the mass spectrum of tert-butyl chloride, the three strongest peaks appear at m/z = 57, 92, and 94. Identify the structure of each.
4. (3 points) Identify the unknown compound that gives the following spectral data.
IR strong, broad absorption at about 3300 cm-1
H-1 NMR 2.0 ppm, 1H
4.0 ppm, 2H
7.5 ppm, 5H