Organic Chemistry II |
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Professor Carl C. Wamser |
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Chem 335 - Winter Term |
Chapter 14 Skills |
Knowledge - Level 1
Terminology:
organometallics, Grignard reagents
carbenes, carbenoids, alpha-elimination
Simmons-Smith reaction
18-electron rule
metallocenes
Ziegler-Natta catalysis
identify bond polarity in organometallic compounds and its effect on reactivity
identify carbenes and carbenoids structure and reactivity
name organometallic compounds
predict products of reactions in organometallic additions to carbonyl compounds, dialkylcuprate coupling reactions, Simmons-Smith cycloadditions
write electron-pushing mechanisms for organometallic addition or coupling reactions
categorize transition metal complex stability based on the 18-electron rule
use retrosynthetic analysis to plan a synthetic sequence of reactions
use organometallic carbon-carbon bond-forming reactions to create an extended carbon framework