Organic Chemistry II |
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Professor Carl C. Wamser |
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Chem 335 - Winter 2004 |
Chapter 10 Homework |
Carey, pages 418 - 422 :
Problems 10.18 - 39
1. Write all the possible stereoisomers that could result from the Diels-Alder reaction of (E,E)-2,4-hexadiene with cis-2-butenedinitrile (cis-1,2-dicyanoethylene).
Given the preference for endo addition and minimizing steric hindrance, predict the major product(s). Would this product be described as racemic, achiral, or optically active?