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Organic Chemistry I |
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Professor Carl C. Wamser |
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Chapter 4 Homework |
Carey, pages 189 - 195 :
Problems 4.20 - 4.51, Spartan 4.1 - 4.4, 4.8, 4.9
1. Given that Kw = [H+] [OH-] = 10-14 , explain why the pKa of H2O is cited as 15.7 and the pKa of H3O+ as -1.7 .
2. The pKa of CH3OH2+ (protonated methanol) is -2.2. Predict the preferred
direction of an equilibrium acid-base
reaction between H3O+ and CH3OH.
3. Write a complete mechanism for the SN1 reaction of t-butyl alcohol with HBr.
4. Write a complete mechanism for the SN2 reaction of HI with methanol.