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Organic Chemistry I |
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Professor Carl C. Wamser |
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Chapter 8 Notes |
Recognizing Nucleophiles
Solvents
The SN2 Mechanism
SN2 Mechanism - Evidence
SN2 Mechanism - Evidence
SN2 Mechanism - R Groups
SN2 Mechanism - X Groups
SN2 Mechanism - Nucleophiles
Solvent Effects on Nucleophilicity
SN1 Mechanism
SN1 Mechanism - Evidence
SN1 Mechanism - Evidence
SN1 Mechanism - R Groups
SN1 Mechanism - X Groups
Solvolysis Reactions
Neighboring Group Effects - Mustard Gases
Phase-Transfer Catalysis
Beta-Elimination Reactions
E2 Elimination Mechanism
E2 Stereochemistry
Zaitsev Rule
E1 Elimination Mechanism
Substitution or Elimination ?
Nucleophile or Base?
Reactivity Patterns
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(steric hindrance) |
(carbocation stability) |
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weak base |
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weak nucl. |
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no base, good nucl. |
weak base |
weak base, poor nucl. |
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poor base |
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weak base, poor nucl. |
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strong base, e.g., OH- |
weak base, e.g., I- |
strong base, e.g., tBuO- |
weak base, e.g., H2O |
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