Chem 334 - Fall 1998 - Organic Chemistry I
Portland State University - Dr. Carl C. Wamser


Chapter 7 - Alkyl Halides

Structure

Vinylic and Aryl Halides

Nomenclature

Dipole Moments

Van der Waals Forces

Boiling Points

Density

Bond Lengths, Strengths

Halogenation of Alkanes

Regioselectivity

Energetics

Mechanism - A radical chain mechanism

Mechanism - Formation of radicals

Mechanism - Chain initiation

Mechanism - Chain propagation

Mechanism - Chain termination

Chain Propagation Steps

Regioselectivity

Hammond's Postulate

Radical stability

Stereochemistry

Allylic Halogenation

Allylic Bromination

The Allyl Radical

Organometallic Compounds

Gilman Reagents