Organic Chemistry I

Chem 334 - Fall 2010

Pre-Quiz 3

Professor Carl C. Wamser

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Your answers must be submitted before 8:30 am, Fri, Oct 8

1. For butane, the highest-energy eclipsed conformation is how much higher in energy than the lowest-energy conformation?

a. 0
b. 3 kJ/mol
c. 14 kJ/mol
* d. 25 kJ/mol
e. 42 kJ/mol

2. In molecular mechanics, the increase in energy caused by bonds that are twisted from their ideal staggered conformation is called

a. bond stretching strain
b. angle bending strain
* c. torsional strain
d. van der Waals strain
e. hydrogen bonding strain

3. In the best conformation of cis-1,4-dimethylcyclohexane, the two methyl groups will occupy which positions?

a. both axial
b. both equatorial
* c. one axial, one equatorial

4. The molecular formula for bicyclo[2.2.1]heptane would be

a. C5 H12
b. C5 H8
c. C7 H14
d. C7 H16
* e. C7 H12

5. The compound with the higher (more negative delta H) heat of combustion would be

a. cis-1,3-dimethylcyclohexane
* b. trans-1,3-dimethylcyclohexane