Organic Chemistry I

Chem 334 - Fall 2007

Pre-Quiz 5

Professor Carl C. Wamser

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Your answers must be submitted before 8:30 am, Mon., Oct. 22

1. The C2-C3 bond in propylene is created from what orbitals?

a. sp3 - sp3
* b. sp2 - sp3
c. sp2 - sp2
d. sp - sp3
e. sp - sp2

2. Dehydration of 3-pentanol is expected to give as the major product

a. 1-pentene
* b. 2-pentene
c. 3-pentene
d. 4-pentene

3. The Zaitsev Rule is used to predict

a. rates of carbocation formation
b. structures of transition states
c. isotope effects
* d. preferred alkene products
e. occurrences of rearrangements

4. The E1 mechanism

a. has a bimolecular rate-determining step
b. requires specific stereochemistry
* c. has the same rate-determining step as an SN1 mechanism
d. leads to alcohol product
e. leads to alkyl halide product

5. The E2 mechanism

a. has a unimolecular rate-determining step
* b. requires specific stereochemistry
c. follows first-order kinetics
d. does not show a kinetic isotope effect
e. is typically run in strong acid