Publications since joining Portland State University


16. Trimethoxyphenyl (TMP) as a Useful Auxiliary for in situ Formation and Reaction of Aryl(TMP)iodonium Salts: Synthesis of Diaryl Ethers. Gallagher, R.; Basu, S.; Stuart, D. R. Adv. Synth. Catal., 2020, 362, 320-325.


15. Analysis of Benzenoid Substitution Patterns in Small Molecule Active Pharmaceutical Ingredients. Nilova, A.; Stuart, D. R. ChemRxiv, 2019,


14. Iodane-Guided C-H Cleavage to Synthesize Densely Functionalized Arenes. Nilova, A.; Sibbald, P. A.; Valente, E.; Gonzalez-Montiel, G. A.; Richardson, H. C.; Brown, K. S.; Cheong, P. H.-Y.; Stuart, D. R. ChemRxiv, 2019,


13. Anion Metathesis of Diaryliodonium Tosylate Salts with a Solid-Phase Column Constructed from Readily Available Laboratory Consumables. Gallagher, R. T.; Seidl, T. L.; Bader, J.; Orella, C.; Vickery, T.; Stuart, D. R. Org. Process Res. Dev., 2019, 23, 1269-1274.


12. Synthesis of 4-Methylbenzoate(2',4',6'-trimethoxyphenyl)iodonium Tosylate. Seidl, T. L.; Moment, A.; Orella, C.; Vickery, T.; Stuart, D. R. Org. Synth., 2019, 96, 137-149.


11. Imide Arylation with Aryl(TMP)iodonium Tosylates. Basu, S.; Sandtorv, A. H.; Stuart, D. R. Beilstein J. Org. Chem., 2018, 14, 1034-1038. (invited contribution for a special issue commemorating the 6th International Conference on Hypervalent Iodine Chemistry)


10. An Admix Approach to Determine Counter Anion Effects on Metal-Free Arylation Reactions with Diaryliodonium Salts. Seidl, T. L.; Stuart, D. R. J. Org. Chem., 2017, 82, 11765-11771. (invited contribution for Specical Issue on Hypervalent Iodine Reagents)


9. Aryl Transfer Selectivity in Metal-Free Reactions of Unsymmetrical Diaryliodonium Salts. Stuart, D. R. Chem. Eur. J., 2017, 23, 15852-15863.


8. Aryl(2,4,6-trimethoxyphenyl)iodonium Salts as Reagents for Metal-Free Arylation of Carbon and Heteroatom Nucleophiles. Stuart, D. R. TCIMAIL, 2017, 2-8. TCI Professor Product Launch Center


7. Synthesis of Aryl(2,4,6-trimethoxyphenyl)iodonium Trifluoroacetate Salts. Carreras, V.; Sandtorv, A. H. Stuart, D. R. J. Org. Chem., 2017, 82, 1279-1284.


6. Unsymmetrical Diaryliodonium Salts as Aryne Synthons: Renaissance of a C-H Deprotonative Approach to Arynes. Stuart, D. R. Synlett, 2017, 28, 275-279 (invited SYNPACTS article)


5. Metal-free Synthesis of Aryl Amines: Beyond Nuclephilic Aromatic Substitution. Sandtorv. A. H.; Stuart, D. R. Angew. Chem. Int. Ed. 2016, 55, 15812 - 15815 (highlighted in Synfacts, 2017, 13, 189; AHS wins Fulbright Norway Article of the Year, 2016).


4. A Selective C-H Deprotonation Strategy to Functionalized Arynes by Using Hypervalent Iodine. Sundalam, S. K.; Nilova, A.; Seidl, T. L.; Stuart, D. R. Angew. Chem. Int. Ed. 2016, 55, 8431 - 8434 (highlighted in Synfacts, 2016, 12, 791)


3. Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies. Seidl, T. L.; Sundalam, S. K.; McCullough, B.; Stuart, D. R. J. Org. Chem. 2016, 81, 1998 - 2009.


2. Base Mediated Synthesis of Alkyl-aryl Ethers from the Reaction of Aliphatic Alcohols and Unsymmetric Diaryliodonium Salts. Sundalam, S. K.; Stuart, D. R. J. Org. Chem. 2015, 80, 6456 - 6466.


1. The Discovery and Development of a Palladium(II)-Catalyzed Oxidative Cross-Coupling of Two Unactivated Arenes. Stuart, D. R.; Fagnou, K. Top. Organomet. Chem. 2013, 44, 91 (book chapter on graduate work).



Publications prior to Portland State University


11. Carbazole-bis(oxazolines) as Monoanionic, Tridentate Chelates in Lanthanide Chemistry: Synthesis and Structural Studies of Thermally Robust and Kinetically Stable Dialkyl and Dichloride Complexes. Zou, J.; Berg, D. J.; Stuart, D.; McDonald, R.; Twamley, B. Organometallics 2011, 30, 4958.


10. The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3-Aliphatic-Substituted Indoles and Pyrroles. Heustis, M. P.; Chan, L.; Stuart, D. R.; Fagnou, K. Angew. Chem. Int. Ed. 2011, 50, 1338.


9. Rhodium(III)-Catalyzed Arene and Alkene C-H Bond Functionalization Leading to Indoles and Pyrroles. Stuart, D. R.; Alsabeh, P.; Kuhn, M.; Fagnou, K. J. Am. Chem. Soc. 2010, 132, 18326.


8. Mechanistic Analysis of Azine N-Oxide Direct Arylation: Evidence for a Critical Role of Acetate in the Pd(OAc)2 Precatalyst. Sun, H.- Y.; Gorelsky, S. I.; Stuart, D. R.; Campeau, L.- C.; Fagnou, K. J. Org. Chem. 2010, 75, 8180.


7. Palladium-Catalyzed Direct Arylation of Azine and Azole N-Oxides: Reaction Development, Scope, and Application in Synthesis. Campeau, L.- C.; Stuart, D. R.; Leclerc, J.- P.; Bertrand-Laperle, M.; Villemure, E.; Sun, H.- Y. ; Guimond, N.; Lasserre, S.; Lecavallier, M.; Fagnou, K. J. Am. Chem. Soc. 2009, 131, 3291.


6. Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes. Stuart, D. R.; Bertrand-Laperle, M.; Burgess, K. M. N.; Fagnou, K. J. Am. Chem. Soc. 2008, 130, 16474.


5. Intramolecular Pd(II)-Catalyzed Oxidative Biaryl Synthesis Under Air : Reaction Development and Scope. Liegault, B.; Lee, D.; Huestis, M. P.; Stuart, D. R.; Fagnou, K. J. Org. Chem., 2008, 73, 5022.


4. Elements of Regiocontrol in Palladium-Catalyzed Oxidative Arene Cross-Coupling. Stuart, D. R.; Villemure, E.; Fagnou, K. J. Am. Chem. Soc., 2007, 129, 12072.


3. The Catalytic Cross-Coupling of Unactivated Arenes. Stuart, D. R.; Fagnou, K. Science, 2007, 316, 1172.


2. Recent Advances in Intermolecular Direct Arylation Reactions. Campeau, L.- C.; Stuart, D. R.; Fagnou, K. Aldrichemica Acta, 2007, 40, 35.


1. Solvent Effects on Hydrogen Abstraction Reactions from Lactones with Antioxidant Properties. Aliaga, C.; Stuart, D. R.; Aspee, A.; Scaiano, J. C. Org. Lett., 2005, 7, 3665.